Product ID:TCL MIX-3 1ML, 48453
MSDS Date:10/26/1988
FSC:6850
NIIN:00N019153
MSDS Number: BLXVK

SUPELCO INC

SUPELCO PARK
BELLEFONTE, PA 16823-0048
US

Emergency Phone: 814-359-3441

Info Phone: 814-359-3441

Cage: 54968

SIGMA-ALDRICH INC.

14508 ST. LOUIS, MO 63103 US

Telephone: 314-771-5765/414-273-3850X5996

Cage: 54968

(ORAL RAT) 5628 MG/KG.

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 98.8%

OSHA PEL S,200PPM/250STEL

ACGIH TLV: S,200PPM/250STEL; 93

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

(ORAL

CAS: 107-06-2

RTECS: KI0525000

Fraction By Weight: 0.2%

OSHA PEL 50 PPM/C,100PPM

ACGIH TLV: 10 PPM; 9293

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

ETHANE, 1,1,1-TRICHLORO-;(1,1,1-TRICHLOROETHANE).

CAS: 71-55-6

RTECS: KJ2975000

Fraction By Weight: 0.2%

OSHA PEL 350 PPM;450 STEL

ACGIH TLV: 350 PPM;450 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

(ORAL RAT) 3500 MG/KG.

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: 0.2%

OSHA PEL 100 PPM;125 STEL

ACGIH TLV: 100 PPM;125 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

(ORAL RAT)

CAS: 127-18-4

RTECS: KX3850000

Fraction By Weight: 0.2%

OSHA PEL 100 PPM

ACGIH TLV: 25PPM/100,A3 STEL;94

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

(ORAL RAT) 5000 MG/KG.

CAS: 106-42-3

RTECS: ZE2625000

Fraction By Weight: 0.2%

OSHA PEL 100 PPM;150 STEL

ACGIH TLV: 100 PPM;150 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

PROPENE, 1,3-DICHLORO;(1,3 DICHLOROPROPENE, MIXTURE OF

CAS: 542-75-6

RTECS: UC8310000

Fraction By Weight: 0.2%

OSHA PEL 1 PPM,S

ACGIH TLV: 1 PPM,S

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

LD50 LC50 Mixture:LD50:(ORAL RAT) 5628 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:HARMFUL IF INHALED. MAY BE FATAL IF
SWALLOWED. CONTAINS MATERIALS KNOWN TO STATE OF CALIFORNIA TO CAUSE
CANCER. HEADACHE, NAUSAEA, GI DISTURBANCES, LIVER DAMAGE, KIDNEY
DAMAGE. REPORTED ANIMAL CARCINO GEN. BLINDNESS. CHLOROCARBON
MATERIALS HAVE PRODUCED SENSITIZATION OF THE MYOCARDIUM TO (SEE
EFTS OF OVEREXPOSURE)
Explanation of Carcinogenicity:1,2-DICHLORETHANE AND
TETRACHLOROETHYLENE: GROUP 2B (IARC), GROUP 2 (NTP).
Effects of Overexposure:HLTH HAZ:EPINEPHRINE IN LABORATORY ANIMALS AND
COULD HAVE A SIMILAR EFFECT IN HUMANS. ADRENOMIMETICS (E.G.,
EPINEPHRINE)MAY BE CONTRAINDICATED EXCEPT FOR LIFE-SUSTAINING USES
IN HUMANS ACUTELY OR CHRO NICALLY EXPOSED TO CHLOROCARBONS .
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYE:FLUSH WITH WATER FOR AT LEAST 15 MINUTES. CALL MD.
SKIN:FLUSH WITH LARGE VOLUMES OF WATER. INHAL:IMMED REMOVE TO FRESH
AIR. IF BREATHING STOPS, GIVE ARTIFICIAL RESPIRATION. CALL MD.
INGEST:NEVER G IVE ANYTING BY MOUTH TO AN UNCON PERSON. NEVER TRY
TO MAKE AN UNCON PERSON VOMIT. GIVE 2 TABLESPOONS OF BAKING SODA IN
A GLASS OF WATER. PRESS FINGERS TO BACK OF TONGUE TO INDUCE VOMIT.
GET MD IMMED.

Lower Limits:6.0%
Upper Limits:36.5%
Extinguishing Media:CO2, DRY CHEMICAL, ALCOHOL FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
AND FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE HCL AND PHOSGENE .

Spill Release Procedures:TAKE UP WITH ABSORBENT MATERIAL. VENTILATE
AREA. ELIMINATE ALL IGNITION SOURCES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:REFRIGERATE IN SEALED CONTAINER. KEEP
AWAY FROM OXIDIZERS. KEEP AWAY FROM SOURCES OF IGNITION. AVOID EYE
OR SKIN CONTACT. AVOID BREATHING VAPORS.
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN THE GENERAL
VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT AND/OR
UV RADIATION MAY CAUSE THE FORMATION OF HCL AND PHOSGENE .

Respiratory Protection:WEAR NIOSH/MSHA APPROVED FACE MASK WITH ORGANIC
VAPOR CANISTER.
Ventilation:USE ONLY IN WELL VENTILATED AREA.
Protective Gloves:RUBBER GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.

HCC:F5
Boiling Pt:B.P. Text:149F,65C
Melt/Freeze Pt:M.P/F.P Text:-144F,-98C
Vapor Pres:100
Vapor Density:1.10
Spec Gravity:.790
Evaporation Rate & Reference:(ETHER=1) >1
Solubility in Water:100
Appearance and Odor:CLEAR COLORLESS LIQUID
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS, CHROMIC ANHYDRIDE, LEAD PERCHLORATE, PERCHLORIC
ACIDS.
Stability Condition to Avoid:NOT APPLICABLE.
Hazardous Decomposition Products:HCL, PHOSGENE .

Waste Disposal Methods:COMPLY WITH ALL APPLICABLE FEDERAL, STATE OR
LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.